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What happens in the dark? Assessing the temporal control of photo-mediated controlled radical polymerizations
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Dolinski, Neil D., Page, Zachariah A., Discekici, Emre H., Meis, David, Lee, In-Hwan, Jones, Glen R., Whitfield, Richard, Pan, Xiangcheng, McCarthy, Blaine G., Shanmugam, Sivaprakash, Kottisch, Veronika, Fors, Brett P., Boyer, Cyrille, Miyake, Garret M., Matyjaszewski, Krzysztof, Haddleton, David M., Read de Alaniz, Javier , Anastasaki, Athina and Hawker, Craig J. (2019) What happens in the dark? Assessing the temporal control of photo-mediated controlled radical polymerizations. Journal of Polymer Science Part A: Polymer Chemistry, 57 (3). pp. 268-273. doi:10.1002/pola.29247 ISSN 0887-624X.
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WRAP-What-happens-dark-assessing-temporal-photo-mediated-polymerizations-Haddleton-2019.pdf - Accepted Version - Requires a PDF viewer. Download (779Kb) | Preview |
Official URL: https://doi.org/10.1002/pola.29247
Abstract
A signature of photo‐mediated controlled polymerizations is the ability to modulate the rate of polymerization by turning the light source ‘on’ and ‘off.’ However, in many reported systems, growth can be reproducibly observed during dark periods. In this study, emerging photo‐mediated controlled radical polymerizations are evaluated with in situ 1H NMR monitoring to assess their behavior in the dark. Interestingly, it is observed that Cu‐mediated systems undergo long‐lived, linear growth during dark periods in organic media.
| Item Type: | Journal Article | ||||||||||||||||||
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| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||||||||||||
| SWORD Depositor: | Library Publications Router | ||||||||||||||||||
| Journal or Publication Title: | Journal of Polymer Science Part A: Polymer Chemistry | ||||||||||||||||||
| Publisher: | Wiley | ||||||||||||||||||
| ISSN: | 0887-624X | ||||||||||||||||||
| Official Date: | 1 February 2019 | ||||||||||||||||||
| Dates: |
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| Volume: | 57 | ||||||||||||||||||
| Number: | 3 | ||||||||||||||||||
| Page Range: | pp. 268-273 | ||||||||||||||||||
| DOI: | 10.1002/pola.29247 | ||||||||||||||||||
| Status: | Peer Reviewed | ||||||||||||||||||
| Publication Status: | Published | ||||||||||||||||||
| Reuse Statement (publisher, data, author rights): | "This is the peer reviewed version of the following article: Dolinski, N. D., Page, Z. A., Discekici, E. H., Meis, D. , Lee, I. , Jones, G. R., Whitfield, R. , Pan, X. , McCarthy, B. G., Shanmugam, S. , Kottisch, V. , Fors, B. P., Boyer, C. , Miyake, G. M., Matyjaszewski, K. , Haddleton, D. M., Alaniz, J. R., Anastasaki, A. and Hawker, C. J. (2019), What happens in the dark? Assessing the temporal control of photo‐mediated controlled radical polymerizations. J. Polym. Sci. Part A: Polym. Chem., 57: 268-273., which has been published in final form at https://doi.org/10.1002/pola.29247. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions." | ||||||||||||||||||
| Access rights to Published version: | Restricted or Subscription Access | ||||||||||||||||||
| Date of first compliant deposit: | 27 February 2019 | ||||||||||||||||||
| Date of first compliant Open Access: | 8 November 2019 | ||||||||||||||||||
| RIOXX Funder/Project Grant: |
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