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On the relationship between the radiative rate constant and the fluorescence intensity in organic fluorophores
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UNSPECIFIED (2001) On the relationship between the radiative rate constant and the fluorescence intensity in organic fluorophores. CHEMICAL PHYSICS LETTERS, 350 (5-6). pp. 509-514. ISSN 0009-2614.
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Abstract
In this Letter we explore the relationship between the radiative constant, k(r), and the lineshape of an emission spectrum for fluorescent organic molecules, in particular tryptophan, We make a number of judicious approximations to the expression given by Strickler and Berg in conjunction with the log-normal function for the lineshape. Our result is a closed form expression for k(r) in terms of the inverse maximum wavelength lambda(max)(-1) which compares well with recent experimental findings for tryptophan residues in proteins. (C) 2001 Elsevier Science B.V. All rights reserved.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry Q Science > QC Physics |
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Journal or Publication Title: | CHEMICAL PHYSICS LETTERS | ||||
Publisher: | ELSEVIER SCIENCE BV | ||||
ISSN: | 0009-2614 | ||||
Official Date: | 28 December 2001 | ||||
Dates: |
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Volume: | 350 | ||||
Number: | 5-6 | ||||
Number of Pages: | 6 | ||||
Page Range: | pp. 509-514 | ||||
Publication Status: | Published |
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