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Rhodium(III) complexes featuring coordinated CF3 appendages
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Emerson-King, Jack, Prokes, Ivan and Chaplin, Adrian B. (2019) Rhodium(III) complexes featuring coordinated CF3 appendages. Chemistry - A European Journal, 25 (25). pp. 6317-6319. doi:10.1002/chem.201901184 ISSN 0947-6539.
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Official URL: https://doi.org/10.1002/chem.201901184
Abstract
The synthesis and characterisation of a homologous series of rhodium 2,2′‐biphenyl complexes featuring intramolecular dative bonding of the nominally inert and weakly coordinating trifluoromethyl group are described. Presence of these interactions is evidenced in the solid state using X‐ray diffraction, with Rh−F contacts of 2.36–2.45 Å, and in solution using NMR spectroscopy, through hindered C−CF3 bond rotation and the presence of time‐averaged 1JRhF and 2JPF coupling.
Item Type: | Journal Article | |||||||||||||||
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Subjects: | Q Science > QD Chemistry | |||||||||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | |||||||||||||||
Library of Congress Subject Headings (LCSH): | Rhodium compounds, Biphenyl compounds | |||||||||||||||
Journal or Publication Title: | Chemistry - A European Journal | |||||||||||||||
Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA | |||||||||||||||
ISSN: | 0947-6539 | |||||||||||||||
Official Date: | 2 May 2019 | |||||||||||||||
Dates: |
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Volume: | 25 | |||||||||||||||
Number: | 25 | |||||||||||||||
Page Range: | pp. 6317-6319 | |||||||||||||||
DOI: | 10.1002/chem.201901184 | |||||||||||||||
Status: | Peer Reviewed | |||||||||||||||
Publication Status: | Published | |||||||||||||||
Access rights to Published version: | Open Access (Creative Commons) | |||||||||||||||
Date of first compliant deposit: | 15 March 2019 | |||||||||||||||
Date of first compliant Open Access: | 10 April 2019 | |||||||||||||||
RIOXX Funder/Project Grant: |
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