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Synthesis and applications to asymmetric catalysis of a series of mono- and bis(diazaphospholidine) ligands
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UNSPECIFIED (2001) Synthesis and applications to asymmetric catalysis of a series of mono- and bis(diazaphospholidine) ligands. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 (21). pp. 2840-2849. ISSN 1472-7781.
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Abstract
The synthesis of a series of closely related mono- and bis(diazaphospholidine) ligands has been achieved using the condensation of a diamine with a bis(dimethylamino)arylphosphine. The resulting ligands have given excellent results in palladium-catalysed allylic substitution reactions to form C-C bonds (up to 89% ee) and C-N bonds (up to 78% ee).
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 1472-7781 | ||||
Official Date: | 7 November 2001 | ||||
Dates: |
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Number: | 21 | ||||
Number of Pages: | 10 | ||||
Page Range: | pp. 2840-2849 | ||||
Publication Status: | Published |
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