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Porous metal–organic frameworks for enhanced performance silicon anodes in lithium-ion batteries
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Malik, Romeo, Loveridge, Melanie, Williams, Luke J., Huang, Qianye, West, Geoffrey D., Shearing, Paul R., Bhagat, Rohit and Walton, Richard I. (2019) Porous metal–organic frameworks for enhanced performance silicon anodes in lithium-ion batteries. Chemistry of Materials, 31 (11). pp. 4156-4165. doi:10.1021/acs.chemmater.9b00933
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WRAP-porous-metal-organic-frameworks-enhanced-silicon-anodes-Walton-2019.pdf - Accepted Version - Requires a PDF viewer. Download (3572Kb) | Preview |
Official URL: https://doi.org/10.1021/acs.chemmater.9b00933
Abstract
Maintaining the physical integrity of electrode microstructures in Li-ion batteries is critical to significantly extend their cycle life. This is especially important for high-capacity anode materials such as silicon, whose operational volume expansion exerts huge internal stress within the anode, resulting in electrode destruction and capacity fade. In this study, we demonstrate that by incorporating metal–organic frameworks (MOFs) with carboxylate organic linkers into Si-based anodes, a stable and flexible pore network is generated to maximize and maintain Li-ion flux throughout the electrode’s architecture. We show that the zirconium carboxylate MOF UiO-67 is a versatile comaterial to boost performance and mitigate the rate of anode degradation that presently limits the lifetime of Si anodes. The cage-like pores in UiO-67 and flexural properties of the 4,4′-biphenyldicarboxylate organic linker are proposed to create robust “ionophores” in the anode film to enhance longer term durability and performance.
| Item Type: | Journal Article | ||||||||||||
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| Subjects: | T Technology > TK Electrical engineering. Electronics Nuclear engineering | ||||||||||||
| Divisions: | Faculty of Science > Chemistry Faculty of Science > WMG (Formerly the Warwick Manufacturing Group) |
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| Library of Congress Subject Headings (LCSH): | Lithium ion batteries | ||||||||||||
| Journal or Publication Title: | Chemistry of Materials | ||||||||||||
| Publisher: | American Chemical Society | ||||||||||||
| ISSN: | 0897-4756 | ||||||||||||
| Official Date: | 15 May 2019 | ||||||||||||
| Dates: |
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| Date of first compliant deposit: | 30 May 2019 | ||||||||||||
| Volume: | 31 | ||||||||||||
| Number: | 11 | ||||||||||||
| Page Range: | pp. 4156-4165 | ||||||||||||
| DOI: | 10.1021/acs.chemmater.9b00933 | ||||||||||||
| Status: | Peer Reviewed | ||||||||||||
| Publication Status: | Published | ||||||||||||
| Access rights to Published version: | Restricted or Subscription Access | ||||||||||||
| Copyright Holders: | © 2019 American Chemical Society | ||||||||||||
| RIOXX Funder/Project Grant: |
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