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Synthesis of enantiomerically-enriched N-aryl amino-amides via a Jocic-type reaction
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Hobson, Christian, Perryman, Michael S., Kirby, Gavin, Clarkson, Guy J. and Fox, David J. (2018) Synthesis of enantiomerically-enriched N-aryl amino-amides via a Jocic-type reaction. Tetrahedron Letters, 59 (44). pp. 3965-3968. doi:10.1016/j.tetlet.2018.09.046 ISSN 0040-4039.
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Official URL: http://dx.doi.org/10.1016/j.tetlet.2018.09.046
Abstract
Enantiomerically-enriched secondary trichloromethyl-alcohols react with aryl amines to give enantiomerically-enriched α-N-arylamino-acid derivatives. The intermediate acid chlorides can react in situ with aryl or, regioselectively, with alkyl amines to give aryl or alkyl α-N-arylamino amides.
Item Type: | Journal Article | |||||||||
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Subjects: | Q Science > QD Chemistry | |||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | |||||||||
Library of Congress Subject Headings (LCSH): | Chemical reactions, Aromatic amines, Enantiomers | |||||||||
Journal or Publication Title: | Tetrahedron Letters | |||||||||
Publisher: | Elsevier | |||||||||
ISSN: | 0040-4039 | |||||||||
Official Date: | 31 October 2018 | |||||||||
Dates: |
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Volume: | 59 | |||||||||
Number: | 44 | |||||||||
Page Range: | pp. 3965-3968 | |||||||||
DOI: | 10.1016/j.tetlet.2018.09.046 | |||||||||
Status: | Peer Reviewed | |||||||||
Publication Status: | Published | |||||||||
Access rights to Published version: | Restricted or Subscription Access | |||||||||
RIOXX Funder/Project Grant: |
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