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5-exo atom transfer cyclisation onto alkynes mediated by copper(I) complexes
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UNSPECIFIED (2001) 5-exo atom transfer cyclisation onto alkynes mediated by copper(I) complexes. TETRAHEDRON LETTERS, 42 (10). pp. 1999-2001. ISSN 0040-4039.
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Abstract
Multidentate amine derived copper(I) halide complexes mediate the atom transfer radical cyclisation of 1-halo-N-propargylacetamides. While cyclisation of trichloro- and dichloroacetamide derivatives leads to alpha,beta -unsaturated gamma -lactams containing the gem-dihalide functional group, monohaloacetamides give rise to either cyclised atom transfer or reduction products depending upon the solvent and catalyst used. (C) 2001 Elsevier Science Ltd. All rights reserved.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | TETRAHEDRON LETTERS | ||||
Publisher: | PERGAMON-ELSEVIER SCIENCE LTD | ||||
ISSN: | 0040-4039 | ||||
Official Date: | 4 March 2001 | ||||
Dates: |
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Volume: | 42 | ||||
Number: | 10 | ||||
Number of Pages: | 3 | ||||
Page Range: | pp. 1999-2001 | ||||
Publication Status: | Published |
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