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Probing the effects of heterocyclic functionality in [(Benzene) Ru(TsDPENR) Cl] catalysts for asymmetric transfer hydrogenation
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Barrios-Rivera, Jonathan, Xu, Yingjian and Wills, Martin (2019) Probing the effects of heterocyclic functionality in [(Benzene) Ru(TsDPENR) Cl] catalysts for asymmetric transfer hydrogenation. Organic Letters, 21 (18). pp. 7223-7227. doi:10.1021/acs.orglett.9b02339 ISSN 1523-7060.
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WRAP-Probing-effects-heterocyclic-functionality-catalysts-transfer-Wills-2019.pdf - Accepted Version - Requires a PDF viewer. Download (1045Kb) | Preview |
Official URL: http://dx.doi.org/10.1021/acs.orglett.9b02339
Abstract
A range of TsDPEN catalysts containing heterocyclic groups on the amine nitrogen atom were prepared and evaluated in the asymmetric transfer hydrogenation of ketones. Bidentate and tridentate ligands demonstrated a mutual exclusivity directly related to their function as catalysts. A broad series of ketones were reduced with these new catalysts, permitting the ready identification of an optimal catalyst for each substrate and revealing the subtle effects that changes to nearby donor groups can exhibit.
Item Type: | Journal Article | |||||||||
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Subjects: | Q Science > QD Chemistry | |||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | |||||||||
Library of Congress Subject Headings (LCSH): | Chemistry, Organic, Hydrogenation, Ketones -- Synthesis | |||||||||
Journal or Publication Title: | Organic Letters | |||||||||
Publisher: | American Chemical Society | |||||||||
ISSN: | 1523-7060 | |||||||||
Official Date: | 20 September 2019 | |||||||||
Dates: |
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Volume: | 21 | |||||||||
Number: | 18 | |||||||||
Page Range: | pp. 7223-7227 | |||||||||
DOI: | 10.1021/acs.orglett.9b02339 | |||||||||
Status: | Peer Reviewed | |||||||||
Publication Status: | Published | |||||||||
Reuse Statement (publisher, data, author rights): | “This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see [insert ACS Articles on Request author-directed link to Published Work, see http://pubs.acs.org/page/policy/articlesonrequest/index.html].” | |||||||||
Access rights to Published version: | Restricted or Subscription Access | |||||||||
Date of first compliant deposit: | 2 August 2019 | |||||||||
Date of first compliant Open Access: | 30 July 2020 | |||||||||
RIOXX Funder/Project Grant: |
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