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Photo-induced copper-RDRP in continuous flow without external deoxygenation

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Marathianos, Arkadios, Liarou, Evelina, Anastasaki, Athina, Whitfield, Richard, Laurel, Matthew, Wemyss, Alan M. and Haddleton, David M. (2019) Photo-induced copper-RDRP in continuous flow without external deoxygenation. Polymer Chemistry, 10 (32). pp. 4402-4406. doi:10.1039/c9py00945k ISSN 1759-9962.

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Official URL: https://doi.org/10.1039/c9py00945k

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Abstract

Photo-induced Cu-RDRP of acrylates in a continuous flow reactor without the need for deoxygenation or externally added reagents. Optimization of the catalyst concentration and the flow rate/residence time leads to well-defined polyacrylates with controlled molecular weights, excellent initiator efficiency, high end-group fidelity polymers and product uniformity. A multifunctional initiator was also used to demonstrate the versatility of the system.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science, Engineering and Medicine > Science > Chemistry
SWORD Depositor: Library Publications Router
Library of Congress Subject Headings (LCSH): Polymerization, Free radical reactions, Organic chemistry, Polymers
Journal or Publication Title: Polymer Chemistry
Publisher: Royal Society of Chemistry (RSC)
ISSN: 1759-9962
Official Date: 19 July 2019
Dates:
DateEvent
19 July 2019Published
6 July 2019Accepted
Volume: 10
Number: 32
Page Range: pp. 4402-4406
DOI: 10.1039/c9py00945k
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Open Access (Creative Commons)
Date of first compliant deposit: 18 October 2019
Date of first compliant Open Access: 18 October 2019
RIOXX Funder/Project Grant:
Project/Grant IDRIOXX Funder NameFunder ID
BINAMA 705041H2020 Marie Skłodowska-Curie Actionshttp://dx.doi.org/10.13039/100010665
UNSPECIFIEDUniversity of Warwickhttp://dx.doi.org/10.13039/501100000741
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