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Photo-induced copper-RDRP in continuous flow without external deoxygenation
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Marathianos, Arkadios, Liarou, Evelina, Anastasaki, Athina, Whitfield, Richard, Laurel, Matthew, Wemyss, Alan M. and Haddleton, David M. (2019) Photo-induced copper-RDRP in continuous flow without external deoxygenation. Polymer Chemistry, 10 (32). pp. 4402-4406. doi:10.1039/c9py00945k
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Official URL: https://doi.org/10.1039/c9py00945k
Abstract
Photo-induced Cu-RDRP of acrylates in a continuous flow reactor without the need for deoxygenation or externally added reagents. Optimization of the catalyst concentration and the flow rate/residence time leads to well-defined polyacrylates with controlled molecular weights, excellent initiator efficiency, high end-group fidelity polymers and product uniformity. A multifunctional initiator was also used to demonstrate the versatility of the system.
| Item Type: | Journal Article | |||||||||
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| Subjects: | Q Science > QD Chemistry | |||||||||
| Divisions: | Faculty of Science > Chemistry | |||||||||
| SWORD Depositor: | Library Publications Router | |||||||||
| Library of Congress Subject Headings (LCSH): | Polymerization, Free radical reactions, Organic chemistry, Polymers | |||||||||
| Journal or Publication Title: | Polymer Chemistry | |||||||||
| Publisher: | Royal Society of Chemistry (RSC) | |||||||||
| ISSN: | 1759-9962 | |||||||||
| Official Date: | 19 July 2019 | |||||||||
| Dates: |
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| Volume: | 10 | |||||||||
| Number: | 32 | |||||||||
| Page Range: | pp. 4402-4406 | |||||||||
| DOI: | 10.1039/c9py00945k | |||||||||
| Status: | Peer Reviewed | |||||||||
| Publication Status: | Published | |||||||||
| Access rights to Published version: | Open Access | |||||||||
| RIOXX Funder/Project Grant: |
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