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Data for UV irradiation of Cu-based complexes with aliphatic amine ligands as used in living radical polymerization
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Liarou, Evelina, Staniforth, Michael, Town, James, Marathianos, Arkadios, Grypioti, Maria, Li, Yongguang, Chang, Yujing, Efstathiou, Spyridon, Hancox, Ellis, Wemyss, Alan M., Wilson, Paul, Jones, Bryn, Aljuaid, Mohammed, Stavros, Vasilios G. and Haddleton, David M. (2019) Data for UV irradiation of Cu-based complexes with aliphatic amine ligands as used in living radical polymerization. [Dataset]
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Plain Text (Readme file)
README.txt - Published Version Available under License Creative Commons Attribution 4.0. Download (818b) |
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Archive (ZIP) (Experimental data)
WRAP Dataset 130197.zip - Published Version Available under License Creative Commons Attribution 4.0. Download (642Mb) |
Abstract
The effect UV irradiation on Cu(II)-based complexes with aliphatic amine ligands is investigated. Four aliphatic amines are used as ligands and Cu(II)Br2 as the metal source for the formation of catalyst complexes that can be used for the photoinduced Cu-RDRP of methyl acrylate. Different characterization techniques such as transient electronic absorption spectroscopy (TEAS), ultraviolet-visible (UV-Vis) spectroscopy, electrospray ionization time of flight mass spectrometry (ESI-ToF-MS) and cyclic voltammetry (CV) are applied in order to provide insights into the catalyst behaviour upon photo-irradiation. The excited-state dynamics, the electrochemical behaviour of the Cu(II)/Cu(I) redox couples and the detection of different species upon complexation of the ligand to the metal center (before and after UV irradiation) are further depicted in the quality of the obtained polymers.
| Item Type: | Dataset | |||||||||
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| Subjects: | Q Science > QC Physics Q Science > QP Physiology |
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| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | |||||||||
| Type of Data: | Experimental data | |||||||||
| Library of Congress Subject Headings (LCSH): | Ultraviolet radiation, Ultraviolet radiation -- Physiological effect, Polymerization, Photochemistry | |||||||||
| Publisher: | University of Warwick, Department of Chemistry | |||||||||
| Official Date: | 12 December 2019 | |||||||||
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| Status: | Not Peer Reviewed | |||||||||
| Publication Status: | Published | |||||||||
| Media of Output (format): | .dat .txt .zip .bin .csv .xy .ami .baf .content .mcf .idx .method .result_c .xml .docx .collect .sample .temp .par .pdf .xwp .xml .dsw | |||||||||
| Access rights to Published version: | Open Access (Creative Commons) | |||||||||
| Copyright Holders: | University of Warwick | |||||||||
| Description: | Experimental data presented in compressed (zipped) format containing 7 folders. Folder Structure: Abbreviations: Software used : |
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| Date of first compliant deposit: | 12 December 2019 | |||||||||
| Date of first compliant Open Access: | 12 December 2019 | |||||||||
| RIOXX Funder/Project Grant: |
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