The Library
Synthesis of racemic chiral-at-metal complexes of the Group 4 metals
Tools
UNSPECIFIED (2000) Synthesis of racemic chiral-at-metal complexes of the Group 4 metals. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 605 (1). pp. 45-54. ISSN 0022-328X.
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Abstract
A protocol for asymmetric synthesis of chiral-at-metal complexes is described, but enantiomerically-enriched products can not be isolated due to formation of complexes between the Group 4 metallocene products and the borane by-products. An efficient method for synthesis of racemic chiral-at-metal metallocenes, through lithium chloride catalysed ligand redistribution reactions, is described. Sterically-hindered racemic chiral-at-metal complexes are prepared by nucleophilic substitution of prochiral dichlorides. (C) 2000 Elsevier Science S.A. All rights reserved.
Item Type: | Journal Article | ||||
---|---|---|---|---|---|
Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF ORGANOMETALLIC CHEMISTRY | ||||
Publisher: | ELSEVIER SCIENCE SA | ||||
ISSN: | 0022-328X | ||||
Official Date: | 30 June 2000 | ||||
Dates: |
|
||||
Volume: | 605 | ||||
Number: | 1 | ||||
Number of Pages: | 10 | ||||
Page Range: | pp. 45-54 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
Request changes or add full text files to a record
Repository staff actions (login required)
View Item |