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Identification of the cobalt(II) chloride 'mixed' solvate Co4Cl8(H2O)(4)(MeCN)(6): the ionic structure trans-[Co(H2O)(2)(MeCN)(4)] trans-[Co(H2O)(2)(MeCN)(2)(CoCl4)(2)]
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UNSPECIFIED (2000) Identification of the cobalt(II) chloride 'mixed' solvate Co4Cl8(H2O)(4)(MeCN)(6): the ionic structure trans-[Co(H2O)(2)(MeCN)(4)] trans-[Co(H2O)(2)(MeCN)(2)(CoCl4)(2)]. TRANSITION METAL CHEMISTRY, 25 (5). pp. 534-536. ISSN 0340-4285.
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Abstract
The structure of the title compound features mononuclear octahedral Co-II cations, trans-[Co(H2O)(2)(MeCN)(4)](2+), and trinuclear anions, trans-[Co(H2O)(2)(MeCN)(2)(CoCl4)(2)](2-); the latter centrosymmetric units contain a central octahedral Co(H2O)(2)(MeCN)(2) moiety with two tetrahedral [CoCl4](2-) ligands. These two large ions are held in a network of intra- and inter-molecular hydrogen bonding.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | TRANSITION METAL CHEMISTRY | ||||
Publisher: | KLUWER ACADEMIC PUBL | ||||
ISSN: | 0340-4285 | ||||
Official Date: | October 2000 | ||||
Dates: |
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Volume: | 25 | ||||
Number: | 5 | ||||
Number of Pages: | 3 | ||||
Page Range: | pp. 534-536 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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