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Crown ether complexation of Hg(II): Synthesis and crystal structure of [(HgCl2)(2)(dibenzo-24-crown-8)]
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UNSPECIFIED (2000) Crown ether complexation of Hg(II): Synthesis and crystal structure of [(HgCl2)(2)(dibenzo-24-crown-8)]. MAIN GROUP METAL CHEMISTRY, 23 (5). pp. 281-284. ISSN 0334-7575.
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Abstract
The dinuclear compound [(HgCl2)(2)(dibenzo-24-crown-8)] has been isolated as colourless, block crystals and structurally characterised by X-ray diffraction studies. The structure is centrosymmetric and consists of a core ClHg(mu-Cl)(2)HgCl unit entrapped within the ring cavity with each metal centre directly bonded to three of the crown oxygen atoms. Hg-Cl-terminal 2.306(4) Angstrom, Hg-Cl-bridging 2.326(4), 3.189(3) Angstrom and Hg-O-crown 2.640(9)- 2.772(8) Angstrom.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | MAIN GROUP METAL CHEMISTRY | ||||
Publisher: | FREUND PUBLISHING HOUSE LTD | ||||
ISSN: | 0334-7575 | ||||
Official Date: | May 2000 | ||||
Dates: |
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Volume: | 23 | ||||
Number: | 5 | ||||
Number of Pages: | 4 | ||||
Page Range: | pp. 281-284 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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