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Applications of ionic liquids in starch chemistry : a review
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Ren, Fei, Wang, Jinwei, Xie, Fengwei, Zan, Ke, Wang, Shuo and Wang, Shujun (2020) Applications of ionic liquids in starch chemistry : a review. Green Chemistry, 22 (7). pp. 2162-2183. doi:10.1039/C9GC03738A ISSN 1463-9262.
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WRAP-applications-ionic-liquids-starch-chemistry-review-Xie-2020.pdf - Accepted Version - Requires a PDF viewer. Download (1685Kb) | Preview |
Official URL: http://dx.doi.org/10.1039/C9GC03738A
Abstract
Recently, the utilization of starch to replace synthetic polymers for the manufacture of green materials has gained extensive interest, due to its renewability, biodegradability, abundance and low cost. On the other hand, ionic liquids (ILs) have been widely recognized as promising “green solvents” to replace volatile organic solvents for polysaccharide processing. Over the past few years, ILs have been increasingly demonstrated to serve as excellent media for the dissolution, plasticization and derivatization of starch. This allows the synthesis of chemically modified starches with high degree of substitution (DS) and the development of various starch-based materials such as thermoplastic starch, composite films, solid polymer electrolytes, nanoparticles and drug carriers. The main objective of this review is to present an overview of the roles of ILs in starch dissolution, gelatinization, modification and plasticization, and their industrial applications. Moreover, this review is intended to provide a comprehensive understanding of the mechanisms behind the IL-processing of starch and to provide insights into the rational development of novel starch-based materials with ILs.
Item Type: | Journal Article | |||||||||
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Subjects: | Q Science > QC Physics Q Science > QK Botany Q Science > QP Physiology T Technology > TP Chemical technology |
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Divisions: | Faculty of Science, Engineering and Medicine > Engineering > WMG (Formerly the Warwick Manufacturing Group) | |||||||||
Library of Congress Subject Headings (LCSH): | Starch , Chemistry, Organic, Ionic solutions , Dissolution (Chemistry), Starch -- Dissolution, Phase transformations (Statistical physics) | |||||||||
Journal or Publication Title: | Green Chemistry | |||||||||
Publisher: | Royal Society of Chemistry | |||||||||
ISSN: | 1463-9262 | |||||||||
Official Date: | 2020 | |||||||||
Dates: |
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Volume: | 22 | |||||||||
Number: | 7 | |||||||||
Page Range: | pp. 2162-2183 | |||||||||
DOI: | 10.1039/C9GC03738A | |||||||||
Status: | Peer Reviewed | |||||||||
Publication Status: | Published | |||||||||
Access rights to Published version: | Restricted or Subscription Access | |||||||||
Date of first compliant deposit: | 7 April 2020 | |||||||||
Date of first compliant Open Access: | 7 February 2021 | |||||||||
RIOXX Funder/Project Grant: |
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