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Structure determination of molecular adsorbates on oxide surfaces using scanned-energy mode photoelectron diffraction
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UNSPECIFIED (1999) Structure determination of molecular adsorbates on oxide surfaces using scanned-energy mode photoelectron diffraction. In: Meeting on the Surface Science of Metal Oxides, ST MARTINS COLL, AMBLESIDE, ENGLAND, SEP 01-03, 1999. Published in: FARADAY DISCUSSIONS (114). pp. 141-155. ISSN 0301-7249.
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Abstract
Using N 1s scanned-energy mode photoelectron diffraction (PhD) combined with full multiple scattering simulations the local adsorption site of NO on NiO(100) has been determined. The molecule bonds through the N atom atop a surface layer N atom, while the N-O axis is tilted away from the surface normal by 59(+31/-17)degrees. The special problems presented by adsorbates on compound surfaces, for the direct inversion of PhD data to provide a first-order site determination, are discussed and some alternative schemes tested.
Item Type: | Conference Item (UNSPECIFIED) | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | FARADAY DISCUSSIONS | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 0301-7249 | ||||
Official Date: | 1999 | ||||
Dates: |
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Number: | 114 | ||||
Number of Pages: | 15 | ||||
Page Range: | pp. 141-155 | ||||
Publication Status: | Published | ||||
Title of Event: | Meeting on the Surface Science of Metal Oxides | ||||
Location of Event: | ST MARTINS COLL, AMBLESIDE, ENGLAND | ||||
Date(s) of Event: | SEP 01-03, 1999 |
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