The Library
Isolated zirconium centres captured from aqueous solution : the structure of zirconium mandelate revealed from NMR crystallography
Tools
Crosland, James M, Corlett, Emily K., Scapens, Dave, Guillou, Nathalie, Brown, Steven P. and Walton, Richard I. (2020) Isolated zirconium centres captured from aqueous solution : the structure of zirconium mandelate revealed from NMR crystallography. Chemical Communications, 56 (7). pp. 10159-10162. doi:10.1039/D0CC03647A ISSN 1359-7345.
|
PDF
WRAP-isolated-zirconium-centres-captured-aqueous-solution-Walton-2020.pdf - Published Version - Requires a PDF viewer. Available under License Creative Commons Attribution. Download (2079Kb) | Preview |
|
PDF
WRAP-isolated-zirconium-centres-captured-aqueous-solution-Walton-2020.pdf - Accepted Version Embargoed item. Restricted access to Repository staff only - Requires a PDF viewer. Download (2069Kb) |
Official URL: https://doi.org/10.1039/D0CC03647A
Abstract
Zirconium tetramandelate (2-hydroxy-2-phenylacetate) has been used for selective gravimetric analysis of zirconium for over 70 years. Herein its crystal structure is reported from synchrotron powder X-ray diffraction and 13C solid-state NMR. The complex is a rare example of isolated zirconium cations, rather than the clusters prevalent in aqueous solutions.
Item Type: | Journal Article | ||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Subjects: | Q Science > QC Physics Q Science > QD Chemistry |
||||||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry Faculty of Science, Engineering and Medicine > Science > Physics |
||||||||||||
Library of Congress Subject Headings (LCSH): | Zirconium, Nuclear magnetic resonance, Crystallography | ||||||||||||
Journal or Publication Title: | Chemical Communications | ||||||||||||
Publisher: | Royal Society of Chemistry | ||||||||||||
ISSN: | 1359-7345 | ||||||||||||
Official Date: | 11 September 2020 | ||||||||||||
Dates: |
|
||||||||||||
Volume: | 56 | ||||||||||||
Number: | 7 | ||||||||||||
Page Range: | pp. 10159-10162 | ||||||||||||
DOI: | 10.1039/D0CC03647A | ||||||||||||
Status: | Peer Reviewed | ||||||||||||
Publication Status: | Published | ||||||||||||
Access rights to Published version: | Open Access (Creative Commons) | ||||||||||||
Date of first compliant deposit: | 9 July 2020 | ||||||||||||
Date of first compliant Open Access: | 15 July 2020 | ||||||||||||
RIOXX Funder/Project Grant: |
|
||||||||||||
Related URLs: |
Request changes or add full text files to a record
Repository staff actions (login required)
View Item |
Downloads
Downloads per month over past year