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Novel catalysts for asymmetric reduction of carbonyl groups
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UNSPECIFIED (1999) Novel catalysts for asymmetric reduction of carbonyl groups. In: 9th International Symposium on the Relations between Homogeneous and Heterogeneous Catalysis (SHHC-9), UNIV SOUTHAMPTON, SOUTHAMPTON, ENGLAND, JUL 19-24, 1998. Published in: JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 146 (1-2). pp. 139-148. ISSN 1381-1169.
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Abstract
The use of (i) enantiomerically pure phosphinamides coupled to borane and (ii) an enantiomerically pure amino alcohol coupled to a transfer hydrogenation process, in the asymmetric catalysis of the reduction of ketones to alcohols, is described. The former process is particularly suited to the reduction of alpha-chlorinated substrates, affording e.e.s of up to 94%, whilst the latter process is optimal for unfunctionalised ketones, affording e.e.s of up to 98%. (C) 1999 Elsevier Science B.V. All rights reserved.
Item Type: | Conference Item (UNSPECIFIED) | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | ||||
Publisher: | ELSEVIER SCIENCE BV | ||||
ISSN: | 1381-1169 | ||||
Official Date: | 20 October 1999 | ||||
Dates: |
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Volume: | 146 | ||||
Number: | 1-2 | ||||
Number of Pages: | 10 | ||||
Page Range: | pp. 139-148 | ||||
Publication Status: | Published | ||||
Title of Event: | 9th International Symposium on the Relations between Homogeneous and Heterogeneous Catalysis (SHHC-9) | ||||
Location of Event: | UNIV SOUTHAMPTON, SOUTHAMPTON, ENGLAND | ||||
Date(s) of Event: | JUL 19-24, 1998 |
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