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Synthesis and [2+2]-photodimerisation of monothiomaleimide functionalised linear and brush-like polymers
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Aljuaid, Mohammed, Liarou, Evelina, Town, James, Baker, James R., Haddleton, David M. and Wilson, Paul (2020) Synthesis and [2+2]-photodimerisation of monothiomaleimide functionalised linear and brush-like polymers. Chemical Communications, 56 (66). pp. 9545-9548. doi:10.1039/D0CC04067C
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WRAP-Synthesis-photodimerisation-monothiomaleimide-linear-brush-polymers-Wilson-2020.pdf - Accepted Version - Requires a PDF viewer. Download (1504Kb) | Preview |
Official URL: http://dx.doi.org/10.1039/D0CC04067C
Abstract
[2+2]-Photodimerisation of monothiomaleimides has been demonstrated on functionalised linear and brush-like polymers. In water/acetonitrile (95 : 5) mixtures the rate of reaction is accelerated significantly by irradiation of the thiomaleimide end group (λmax = 350 nm) with UV light, reaching full conversion within 10 minutes.
| Item Type: | Journal Article | |||||||||
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| Subjects: | Q Science > QD Chemistry | |||||||||
| Divisions: | Faculty of Science > Chemistry | |||||||||
| Library of Congress Subject Headings (LCSH): | Polymers, Polymerization, Photochemistry -- Research | |||||||||
| Journal or Publication Title: | Chemical Communications | |||||||||
| Publisher: | Royal Society of Chemistry | |||||||||
| ISSN: | 1359-7345 | |||||||||
| Official Date: | 25 August 2020 | |||||||||
| Dates: |
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| Date of first compliant deposit: | 28 July 2020 | |||||||||
| Date of first compliant Open Access: | 14 July 2021 | |||||||||
| Volume: | 56 | |||||||||
| Number: | 66 | |||||||||
| Page Range: | pp. 9545-9548 | |||||||||
| DOI: | 10.1039/D0CC04067C | |||||||||
| Status: | Peer Reviewed | |||||||||
| Publication Status: | Published | |||||||||
| Access rights to Published version: | Restricted or Subscription Access | |||||||||
| RIOXX Funder/Project Grant: |
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