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Synthesis and [2+2]-photodimerisation of monothiomaleimide functionalised linear and brush-like polymers

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Aljuaid, Mohammed, Liarou, Evelina, Town, James, Baker, James R., Haddleton, David M. and Wilson, Paul (2020) Synthesis and [2+2]-photodimerisation of monothiomaleimide functionalised linear and brush-like polymers. Chemical Communications, 56 (66). pp. 9545-9548. doi:10.1039/D0CC04067C ISSN 1359-7345.

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Official URL: http://dx.doi.org/10.1039/D0CC04067C

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Abstract

[2+2]-Photodimerisation of monothiomaleimides has been demonstrated on functionalised linear and brush-like polymers. In water/acetonitrile (95 : 5) mixtures the rate of reaction is accelerated significantly by irradiation of the thiomaleimide end group (λmax = 350 nm) with UV light, reaching full conversion within 10 minutes.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science, Engineering and Medicine > Science > Chemistry
Library of Congress Subject Headings (LCSH): Polymers, Polymerization, Photochemistry -- Research
Journal or Publication Title: Chemical Communications
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Official Date: 25 August 2020
Dates:
DateEvent
25 August 2020Published
14 July 2020Available
14 July 2020Accepted
Volume: 56
Number: 66
Page Range: pp. 9545-9548
DOI: 10.1039/D0CC04067C
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Restricted or Subscription Access
Date of first compliant deposit: 28 July 2020
Date of first compliant Open Access: 14 July 2021
RIOXX Funder/Project Grant:
Project/Grant IDRIOXX Funder NameFunder ID
URF\R1\180274Royal Societyhttp://dx.doi.org/10.13039/501100000288
URF\R1\180274Tata Grouphttp://viaf.org/viaf/132378958/

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