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N,N '-Unsubstituted amidinato metallacycle complexes of Group 13 metal alkyls: the crystal structure of trimeric [{Me2Al(mu-HNCPhNH)}(3)]
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UNSPECIFIED (1999) N,N '-Unsubstituted amidinato metallacycle complexes of Group 13 metal alkyls: the crystal structure of trimeric [{Me2Al(mu-HNCPhNH)}(3)]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 586 (2). pp. 138-144. ISSN 0022-328X.
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Abstract
The amidinato complexes [Me2ML] (L = HNCPhNH, M = Al, Ga, In; L = (HNCBuNH)-N-t, M = Ga) result from the reaction of the trialkylmetal with an equimolar amount of the amidine. MS data indicate that the complexes exist as dimers or trimers in the gas phase. X-ray crystallographic studies on [(Me2Al(mu-KNCPhNH)}(3)] (1) reveal a novel trimeric structure in the solid state, with bridging benzamidinato ligands, and a 12-membered metallacycle. Reaction of InMe3 with two moles of benzamidine yields a cyclic imidoylamidinato derivative with a six-membered [InNCNCN] ring. (C) 1999 Elsevier Science S.A. All rights reserved.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF ORGANOMETALLIC CHEMISTRY | ||||
Publisher: | ELSEVIER SCIENCE SA | ||||
ISSN: | 0022-328X | ||||
Official Date: | 5 September 1999 | ||||
Dates: |
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Volume: | 586 | ||||
Number: | 2 | ||||
Number of Pages: | 7 | ||||
Page Range: | pp. 138-144 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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