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Data for Exploring the synthesis and coordination chemistry of pentafluorophenylcopper : organocopper polyanions and coordination networks
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Murray-Watson, Rebecca J. and Pike, Sebastian D. (2020) Data for Exploring the synthesis and coordination chemistry of pentafluorophenylcopper : organocopper polyanions and coordination networks. [Dataset]
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Archive (ZIP) (Zip archive)
Dataset to support article Exploring the Synthesis and Coordination Chemistry of Pentafluorophenyl-Copper Organocopper Polyanions and Coordination Networks.zip - Unspecified Version Available under License Creative Commons Attribution 4.0. Download (50Mb) |
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Plain Text (Readme file)
Readme (1).txt - Published Version Available under License Creative Commons Attribution 4.0. Download (609b) |
Abstract
[Cu-C6F5]4 is a thermally stable and soluble compound with suitable reactivity for synthetic applications in organic and inorganic chemistry. Here the synthesis of [Cu-C6F5]4 is explored in different solvents and followed by in-situ 19F NMR spectroscopy. The importance of solvent choice during the synthesis from Grignard reagent C6F5MgBr is highlighted, with a range of magnesium cuprate species identified and isolated when THF is used as solvent (rather than Et2O), including [Cu(C6F5)2]– and the remarkable organocopper polyanion ([Cu5(C6F5)7]2–)∞. The coordination chemistry of [Cu-C6F5]4 with 1,4-dioxane is investigated in solution and in the solid state, with an extended coordination network, [Cu-C6F5]4(dioxane),structurally resolved for the first time. This structure reveals interwoven linear and zig-zag chains featuring dioxane donors unusually coordinating to adjacent Cu sites of some of the [Cu-C6F5]4 tetramers.
| Item Type: | Dataset | |||||||||
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| Subjects: | Q Science > QD Chemistry | |||||||||
| Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | |||||||||
| Type of Data: | Experimental data | |||||||||
| Library of Congress Subject Headings (LCSH): | Organocopper compounds -- Synthesis, Chemistry, Organic, Chemical reactions | |||||||||
| Publisher: | Department of Chemistry | |||||||||
| Official Date: | 14 October 2020 | |||||||||
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| Status: | Not Peer Reviewed | |||||||||
| Publication Status: | Published | |||||||||
| Media of Output (format): | .csv .mnova .pdf .opj | |||||||||
| Access rights to Published version: | Open Access (Creative Commons) | |||||||||
| Copyright Holders: | University of Warwick | |||||||||
| Description: | Data record consists of a zip archive and an accompanying readme file. |
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| Date of first compliant deposit: | 19 October 2020 | |||||||||
| Date of first compliant Open Access: | 19 October 2020 | |||||||||
| RIOXX Funder/Project Grant: |
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