The Library
Tris (2-pyridylmethyl)triazacyclododecane complexes of Fe-II and Cu-II
Tools
UNSPECIFIED (1999) Tris (2-pyridylmethyl)triazacyclododecane complexes of Fe-II and Cu-II. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 55 (Part 6). pp. 886-889. ISSN 0108-2701.
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Abstract
The title complexes, [1,5,9-tris(2-pyridylmethyl)1,5,9- triazacyclododecane-kappa(3)N] iron(II) tetrachloroferrate, [Fe(C27H36N6)][FeCl4], and [1,5,9-tris(2-pyridylmethyl)-1,5,9-triazacyclododecane-kappa(3)N]copper(III) bis(hexafluorophosphate) acetonitrile hemisolvate, [Cu(C27H36N6)](PF6)(2). 0.5CH(3)CN, differ significantly in their conformations. The iron complex is near-octahedral with Fe-N distances of 2.257 (5) (ring) and 2.226(5)Angstrom (pyridine), and fused chelate rings predominately in the boat form. The copper complex is tetragonally distorted, with four shorter and two longer Cu-N bonds [2.049(6)-2.199(7) and 2.280 (6)-2.473 (7) Angstrom, respectively]; its chelate rings are disordered in boat, chair and skew forms.
Item Type: | Journal Article | ||||
---|---|---|---|---|---|
Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | ||||
Publisher: | MUNKSGAARD INT PUBL LTD | ||||
ISSN: | 0108-2701 | ||||
Official Date: | 15 June 1999 | ||||
Dates: |
|
||||
Volume: | 55 | ||||
Number: | Part 6 | ||||
Number of Pages: | 4 | ||||
Page Range: | pp. 886-889 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
Request changes or add full text files to a record
Repository staff actions (login required)
View Item |