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Stereoselectivity in amidyl radical cyclisations: Alkyl mode cyclisations
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UNSPECIFIED (1999) Stereoselectivity in amidyl radical cyclisations: Alkyl mode cyclisations. SYNLETT (4). pp. 444-446. ISSN 0936-5214.
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Abstract
Amidyl radicals 2 generated from tributylstannane mediated homolysis of O-benzoyl hydroxamic acid derivatives 6a-g undergo alkyl mode 5-exo cyclisation to give mixtures of cis and trans N-acyl pyrrolidinones (d.e. = 54-74%). The efficiency of the process was found to be dependant upon the steric and electronic nature of the nitrogen substituent.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | SYNLETT | ||||
Publisher: | GEORG THIEME VERLAG | ||||
ISSN: | 0936-5214 | ||||
Official Date: | April 1999 | ||||
Dates: |
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Number: | 4 | ||||
Number of Pages: | 3 | ||||
Page Range: | pp. 444-446 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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