README_Thermocouple Tests To ensure validity of the of the experimental thermocouple measurements from the large temperature jump tests, the thermocouples were placed in an insulated vessel of hot water. The water was unmixed, the thermocouples were left to record the temperature as the water cooled to assess the difference between them. In the attached data, the standard deviation has been calculated and there are two plots showing the error bounds from the mean average temperature reading. This was performed as the most likely error will come from the data acquisition device itself. The DAQ device was an NI 9214 TC module plugged into a cDAQ-9178 chassis. The 9214 module specification sheet is attached. The largest error is likely to come from the cold junction, the module used has an isothermal terminal block to reduce this. The quoted typical value of error (not the maximum value), at high resolution sampling at 100C and 0C is 0.37 and 0.36C +/-. The standard deviation plot with the error bounding is within this value. The data reported in the paper which relies on the temperature measurements is the enthalpy of reaction. The enthalpy value is plotted based on the rate of change and achieved using a best fit over many thousands of data points. The value itself is an estimate as stated but the error should be small due to the method taken. The irreproducibility of the reported results will come from the salt itself as many factors could affect the onset of reaction - such as the purity of the water used to prepare the samples, or whether the salt has been left overnight before the test runs. To evaluate the error or uncertainty in any value would be incredibly small, but reproducing the result could still show a discrepancy. None the less the constants derived in the model - which aren't derived from temperature readings - still approximate the reaction rate well.