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Oxidation of 5‐hydroxymethyl furfural to 2,5‐furan dicarboxylic acid under mild aqueous conditions catalysed by MIL‐100(Fe) metal‐organic framework
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Chamberlain, Thomas W., Degirmenci, Volkan and Walton, Richard I. (2022) Oxidation of 5‐hydroxymethyl furfural to 2,5‐furan dicarboxylic acid under mild aqueous conditions catalysed by MIL‐100(Fe) metal‐organic framework. ChemCatChem, 14 (7). e202200135. doi:10.1002/cctc.202200135 ISSN 1867-3880.
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WRAP-oxidation-5‐hydroxymethyl-furfural-2,5‐furan-dicarboxylic-acid-under-mild-aqueous-conditions-catalysed-MIL‐100(Fe)-metal‐organic-framework-Walton-2022.pdf - Accepted Version - Requires a PDF viewer. Download (758Kb) | Preview |
Official URL: http://dx.doi.org/10.1002/cctc.202200135
Abstract
We present the use of the redox active MIL-100(Fe) metalorganic framework (MOF) as a catalyst for the oxidation of 5hydroxymethyl furfural (HMF) into 2,5-furan dicarboxylic acid (FDCA) in water. The MOF is synthesised in water alone under mild hydrothermal conditions and 1 H NMR is used to analyse the products of HMF oxidation. The MOF in combination with the co-catalyst TEMPO provides a total selectivity of desired products of 74% with a maximum FDCA yield of 57% seen after 24 hours at only 70 °C. The catalyst is recycled five times with no loss in activity and no evidence of a reduction to the crystallinity of the MOF.
Item Type: | Journal Article | ||||||||
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Subjects: | Q Science > QD Chemistry | ||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||
Library of Congress Subject Headings (LCSH): | Metal-organic frameworks , Oxidation , Biomass , Furans -- Oxidation | ||||||||
Journal or Publication Title: | ChemCatChem | ||||||||
Publisher: | Wiley - V C H Verlag GmbH & Co. KGaA | ||||||||
ISSN: | 1867-3880 | ||||||||
Official Date: | 7 April 2022 | ||||||||
Dates: |
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Volume: | 14 | ||||||||
Number: | 7 | ||||||||
Article Number: | e202200135 | ||||||||
DOI: | 10.1002/cctc.202200135 | ||||||||
Status: | Peer Reviewed | ||||||||
Publication Status: | Published | ||||||||
Reuse Statement (publisher, data, author rights): | This is the peer reviewed version of the following article: Chamberlain, T..W., Degirmenci, V. and Walton, R..I. (2022), Oxidation of 5-Hydroxymethyl Furfural to 2,5-Furan Dicarboxylic Acid Under Mild Aqueous Conditions Catalysed by MIL-100(Fe) Metal-organic Framework. ChemCatChem. , which has been published in final form at https://doi.org/10.1002/cctc.202200135. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited. | ||||||||
Access rights to Published version: | Restricted or Subscription Access | ||||||||
Date of first compliant deposit: | 18 February 2022 | ||||||||
Date of first compliant Open Access: | 16 February 2023 | ||||||||
RIOXX Funder/Project Grant: |
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