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Unusual features in the triplet state EPR spectrum of 3,5-dichloro-4-aminophenyl cation
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UNSPECIFIED (1997) Unusual features in the triplet state EPR spectrum of 3,5-dichloro-4-aminophenyl cation. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 108 (2-3). pp. 149-153. ISSN 1010-6030.
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Abstract
The tripler ground state of the 3,5-dichloro-aminophenyl cation (Ar-3(+)), generated by photolysis at 77 K of the parent arenediazonium salt, exhibits the strongest dipolar interaction in its EPR spectrum (D > 0.3 cm(-1)) found so far for any known aryl cation. It also shows high-energy site splitting, as detected by EPR for several other cations, producing two distinct forms (type A with D = 0.3066 cm(-1) and type B with D = 0.3410 cm(-1)). Ar-3(+) and certain other aryl cations also show electronic absorption spectra composed of two or three distinct bands. (C) 1997 Elsevier Science S.A.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | ||||
Publisher: | ELSEVIER SCIENCE SA LAUSANNE | ||||
ISSN: | 1010-6030 | ||||
Official Date: | 15 August 1997 | ||||
Dates: |
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Volume: | 108 | ||||
Number: | 2-3 | ||||
Number of Pages: | 5 | ||||
Page Range: | pp. 149-153 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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