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Heterocycle-containing Noyori–Ikariya catalysts for asymmetric transfer hydrogenation of ketones
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Khamis, Noha, Clarkson, Guy J. and Wills, Martin (2022) Heterocycle-containing Noyori–Ikariya catalysts for asymmetric transfer hydrogenation of ketones. Dalton Transactions, 51 (35). pp. 13462-13469. doi:10.1039/D2DT02411J ISSN 1477-9226.
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WRAP-Heterocycle-containing-Noyori-Ikariya-catalysts-for-asymmetric-transfer-hydrogenation-of-ketones-Wills-2022.pdf - Published Version - Requires a PDF viewer. Available under License Creative Commons Attribution 4.0. Download (672Kb) | Preview |
Official URL: http://dx.doi.org/10.1039/D2DT02411J
Abstract
The synthesis of a range of N-(heterocyclesulfonyl)-functionalised Noyori–Ikariya catalysts is described. The complexes were prepared through a short sequence from C2-symmetric 1,2-diphenylethylene-1,2-diamine (DPEN) and were characterised by a range of methods including X-ray crystallography. The complexes were active catalysts for the asymmetric transfer hydrogenation (ATH) of a range of acetophenone derivatives, giving products of high ee in most cases, with notably good results for ortho-substituted acetophenones.
Item Type: | Journal Article | ||||||||||
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Subjects: | Q Science > QD Chemistry | ||||||||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||||||
Library of Congress Subject Headings (LCSH): | Hydrogenation, Ketones , X-ray crystallography | ||||||||||
Journal or Publication Title: | Dalton Transactions | ||||||||||
Publisher: | Royal Society of Chemistry | ||||||||||
ISSN: | 1477-9226 | ||||||||||
Official Date: | 21 September 2022 | ||||||||||
Dates: |
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Volume: | 51 | ||||||||||
Number: | 35 | ||||||||||
Page Range: | pp. 13462-13469 | ||||||||||
DOI: | 10.1039/D2DT02411J | ||||||||||
Status: | Peer Reviewed | ||||||||||
Publication Status: | Published | ||||||||||
Access rights to Published version: | Open Access (Creative Commons) | ||||||||||
Date of first compliant deposit: | 13 September 2022 | ||||||||||
Date of first compliant Open Access: | 13 September 2022 | ||||||||||
RIOXX Funder/Project Grant: |
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