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Polymers without petrochemicals : sustainable routes to conventional monomers
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Hayes, Graham, Laurel, Matthew, MacKinnon, Dan, Zhao, Tieshuai, Houck, Hannes A. and Becer, C. Remzi (2022) Polymers without petrochemicals : sustainable routes to conventional monomers. Chemical Reviews, 123 (5). pp. 2609-2734. doi:10.1021/acs.chemrev.2c00354 ISSN 0009-2665.
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Official URL: https://doi.org/10.1021/acs.chemrev.2c00354
Abstract
Access to a wide range of plastic materials has been rationalized by the increased demand from growing populations and the development of high-throughput production systems. Plastic materials at low costs with reliable properties have been utilized in many everyday products. Multibillion-dollar companies are established around these plastic materials, and each polymer takes years to optimize, secure intellectual property, comply with the regulatory bodies such as the Registration, Evaluation, Authorisation and Restriction of Chemicals and the Environmental Protection Agency and develop consumer confidence. Therefore, developing a fully sustainable new plastic material with even a slightly different chemical structure is a costly and long process. Hence, the production of the common plastic materials with exactly the same chemical structures that does not require any new registration processes better reflects the reality of how to address the critical future of sustainable plastics. In this review, we have highlighted the very recent examples on the synthesis of common monomers using chemicals from sustainable feedstocks that can be used as a like-for-like substitute to prepare conventional petrochemical-free thermoplastics.
Item Type: | Journal Article | |||||||||
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Subjects: | Q Science > QD Chemistry T Technology > TP Chemical technology |
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Divisions: | Other > Institute of Advanced Study Faculty of Science, Engineering and Medicine > Science > Chemistry |
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SWORD Depositor: | Library Publications Router | |||||||||
Library of Congress Subject Headings (LCSH): | Polymers , Petroleum chemicals, Petroleum chemicals -- Environmental aspects, Thermoplastics , Green chemistry | |||||||||
Journal or Publication Title: | Chemical Reviews | |||||||||
Publisher: | American Chemical Society | |||||||||
ISSN: | 0009-2665 | |||||||||
Official Date: | 8 March 2022 | |||||||||
Dates: |
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Volume: | 123 | |||||||||
Number: | 5 | |||||||||
Page Range: | pp. 2609-2734 | |||||||||
DOI: | 10.1021/acs.chemrev.2c00354 | |||||||||
Status: | Peer Reviewed | |||||||||
Publication Status: | Published | |||||||||
Access rights to Published version: | Open Access (Creative Commons) | |||||||||
Date of first compliant deposit: | 8 November 2022 | |||||||||
Date of first compliant Open Access: | 9 November 2022 | |||||||||
RIOXX Funder/Project Grant: |
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