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A single particle model with electrolyte and side reactions for degradation of lithium-ion batteries
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Planella, Ferran Brosa and Widanage, W. Dhammika (2023) A single particle model with electrolyte and side reactions for degradation of lithium-ion batteries. Applied Mathematical Modelling, 121 . pp. 586-610. doi:10.1016/j.apm.2022.12.009 ISSN 0307-904X.
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Official URL: https://doi.org/10.1088/1361-6641/ac5f69
Abstract
Battery degradation, which is the reduction of performance over time, is one of the main roadblocks to the wide deployment of lithium-ion batteries. Physics-based models, such as those based on the Doyle-Fuller-Newman model, are invaluable tools to understand and predict such phenomena. However, these models are often too complex for practical applications, so reduced models are needed. In this article we introduce the Single Particle Model with electrolyte and Side Reactions, a reduced model with electrochemical degradation which has been formally derived from the Doyle-Fuller-Newman model with Side Reactions using asymptotic methods. The reduced model has been validated against the full model for three scenarios (solid-electrolyte interphase growth, lithium plating, and both effects combined) showing similar accuracy at a much lower computational cost. The implications of the results are twofold: the reduced model is simple and accurate enough to be used in most real practical applications, and the reduction framework used is robust so it can be extended to account for further degradation effects.
Item Type: | Journal Article | ||||||||||||
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Subjects: | Q Science > QA Mathematics T Technology > TA Engineering (General). Civil engineering (General) |
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Divisions: | Faculty of Science, Engineering and Medicine > Science > Mathematics Faculty of Science, Engineering and Medicine > Engineering > WMG (Formerly the Warwick Manufacturing Group) |
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SWORD Depositor: | Library Publications Router | ||||||||||||
Library of Congress Subject Headings (LCSH): | Lithium ion batteries, Asymptotic symmetry (Physics), Electrolytes | ||||||||||||
Journal or Publication Title: | Applied Mathematical Modelling | ||||||||||||
Publisher: | Elsevier | ||||||||||||
ISSN: | 0307-904X | ||||||||||||
Official Date: | September 2023 | ||||||||||||
Dates: |
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Volume: | 121 | ||||||||||||
Page Range: | pp. 586-610 | ||||||||||||
DOI: | 10.1016/j.apm.2022.12.009 | ||||||||||||
Status: | Peer Reviewed | ||||||||||||
Publication Status: | Published | ||||||||||||
Access rights to Published version: | Open Access (Creative Commons) | ||||||||||||
Date of first compliant deposit: | 26 May 2023 | ||||||||||||
Date of first compliant Open Access: | 26 May 2023 | ||||||||||||
RIOXX Funder/Project Grant: |
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