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Experimental study of sidewall rupture of cylindrical lithium-ion batteries under radial nail penetration

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Chen, Haodong, Kalamaras, Evangelos, Abaza, Ahmed, Tripathy, Yashraj, Page, Jason and Barai, Anup (2022) Experimental study of sidewall rupture of cylindrical lithium-ion batteries under radial nail penetration. Journal of The Electrochemical Society, 169 (12). 120528. doi:10.1149/1945-7111/acadac ISSN 1945-7111.

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Official URL: https://doi.org/10.1149/1945-7111/acadac

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Abstract

To understand the relationship of the sidewall rupture at different states of charge (SOCs) of cylindrical cells with high specific energy, this work presents the results of radial nail penetration tests of 21700-format cylindrical cells at different SOCs. The thermal runaway and sidewall rupture behaviours were characterised by key performance indicators such as temperature, mass, fire behaviour, and voltage change. In addition, released gases from a subset of tests were measured using the Fourier transform infrared spectroscopy. The change in the internal structure of another subset of cells after the test was observed by X-ray computed tomography. The results show that the sidewall rupture still exists for tests at low SOC (< 30% SOC), but the outcome of thermal runaway and sidewall rupture is milder than those at high SOC (≥ 50% SOC). The average mass loss of cells increases with the increment of SOC. The cell casing thickness is reduced by 12.7% ± 0.3% of the fresh cell, which in combination with the reduction in the strength of the casing material at high temperatures could contribute to sidewall rupture.

Item Type: Journal Article
Subjects: T Technology > TK Electrical engineering. Electronics Nuclear engineering
Divisions: Faculty of Science, Engineering and Medicine > Engineering > WMG (Formerly the Warwick Manufacturing Group)
SWORD Depositor: Library Publications Router
Library of Congress Subject Headings (LCSH): Lithium ion batteries -- Storage, Lithium ion batteries -- Safety measures, Lithium ion batteries -- Research
Journal or Publication Title: Journal of The Electrochemical Society
Publisher: IOP Publishing
ISSN: 1945-7111
Official Date: 30 December 2022
Dates:
DateEvent
30 December 2022Published
Volume: 169
Number: 12
Number of Pages: 12
Article Number: 120528
DOI: 10.1149/1945-7111/acadac
Status: Peer Reviewed
Publication Status: Published
Access rights to Published version: Open Access (Creative Commons)
Date of first compliant deposit: 21 March 2023
Date of first compliant Open Access: 22 March 2023
RIOXX Funder/Project Grant:
Project/Grant IDRIOXX Funder NameFunder ID
Catapult fundingJaguar Land Rover (Firm)http://viaf.org/viaf/305209406
FIRG028Faraday Technologyhttp://dx.doi.org/10.13039/100006587
UNSPECIFIEDInnovate UKhttp://dx.doi.org/10.13039/501100006041

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