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MOF/polymer hybrids through in situ free radical polymerization in metal-organic frameworks
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Pander, Marzena, Gil-San-Millan, Rodrigo, Delgado, Pedro, Perona-Bermejo, Cristina, Kostrzewa, Urszula, Kaczkowski, Karol, Kubicki, Dominik J., Navarro, Jorge A. R. and Bury, Wojciech (2023) MOF/polymer hybrids through in situ free radical polymerization in metal-organic frameworks. Materials Horizons, 10 (4). pp. 1301-1308. doi:10.1039/d2mh01202b ISSN 2051-6347.
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WRAP-MOF-polymer-hybrids-through-in-situ-free-radical-polymerization-in-metal-organic-frameworks-Kubicki-2023.pdf - Published Version - Requires a PDF viewer. Available under License Creative Commons Attribution 4.0. Download (2873Kb) | Preview |
Official URL: http://dx.doi.org/10.1039/d2mh01202b
Abstract
We use the free radical polymerization initiator 4,4′-azobis(cyanovaleric acid) coordinated to the open metal sites of metal-organic frameworks (MOFs) to give rise to highly uniform MOF/polymer hybrids. We demonstrate this strategy on two robust zirconium MOFs (NU-1000 and MOF-808), which are the most effective catalysts for degradation of chemical warfare nerve agents. The resulting hybrid materials maintain their hydrolytic catalytic activity and have substantially improved adhesion to polypropylene and activated carbon textile fibers, yielding highly robust MOF/polymer/textile hybrid systems. These composites are suitable for the green production of active protective clothing and filters capable of detoxifying organophosphorus warfare agents.
Item Type: | Journal Article | |||||||||||||||||||||||||||||||||
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Subjects: | Q Science > QD Chemistry T Technology > TA Engineering (General). Civil engineering (General) T Technology > TP Chemical technology |
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Divisions: | Faculty of Science, Engineering and Medicine > Science > Physics | |||||||||||||||||||||||||||||||||
Library of Congress Subject Headings (LCSH): | Metal-organic frameworks , Polymerization, Free radical reactions, Polymers -- Analysis, Zirconium | |||||||||||||||||||||||||||||||||
Journal or Publication Title: | Materials Horizons | |||||||||||||||||||||||||||||||||
Publisher: | Royal Society of Chemistry | |||||||||||||||||||||||||||||||||
ISSN: | 2051-6347 | |||||||||||||||||||||||||||||||||
Official Date: | 1 April 2023 | |||||||||||||||||||||||||||||||||
Dates: |
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Volume: | 10 | |||||||||||||||||||||||||||||||||
Number: | 4 | |||||||||||||||||||||||||||||||||
Page Range: | pp. 1301-1308 | |||||||||||||||||||||||||||||||||
DOI: | 10.1039/d2mh01202b | |||||||||||||||||||||||||||||||||
Status: | Peer Reviewed | |||||||||||||||||||||||||||||||||
Publication Status: | Published | |||||||||||||||||||||||||||||||||
Access rights to Published version: | Open Access (Creative Commons) | |||||||||||||||||||||||||||||||||
Date of first compliant deposit: | 7 March 2023 | |||||||||||||||||||||||||||||||||
Date of first compliant Open Access: | 8 March 2023 | |||||||||||||||||||||||||||||||||
RIOXX Funder/Project Grant: |
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