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Data for "A composite of Nb2O5 and MoO2 as a high-capacity high-rate anode material for li-ion batteries"

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Walton, Richard I., Wheeler-Jones, Evé and Loveridge, Melanie (2023) Data for "A composite of Nb2O5 and MoO2 as a high-capacity high-rate anode material for li-ion batteries". [Dataset] (In Press)

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Official URL: http://dx.doi.org/10.1002/batt.202200556

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Abstract

A composite of Nb2O5 and MoO2 was synthesised using a hydrothermal reaction (225 C) followed by a short heat-treatment step (600 C) to achieve a high-capacity, high-rate anode for Li-ion battery applications. The composite was shown via powder X-ray diffraction and electron microscopy to be an intimate mix of individual oxide particles rather than an atomically mixed oxide material. The composite was shown by X-ray fluorescence spectroscopy (XRF) to contain a 45:55 ratio of Nb:Mo. This composite oxide is demonstrated to show notable rate capability in Li half-cell cycling and rate tests. When cycled at 100C this material achieved over 100 mAhg-1 even after 400 cycles and shows a stable reversible capacity of 514 mAhg-1 (at 1C), realising its theoretical capacity. This composite shows electrochemical results comparable to Nb2O5:C composites yet achieves far higher capacities at low-rate due to the MoO2 content.

Item Type: Dataset
Subjects: Q Science > Q Science (General)
Divisions: Faculty of Science, Engineering and Medicine > Science > Chemistry
Faculty of Science, Engineering and Medicine > Engineering > WMG (Formerly the Warwick Manufacturing Group)
Type of Data: Asii data (spreadheet) underpinning published paper
Publisher: University of Warwick, WMG
Official Date: 13 March 2023
Dates:
DateEvent
13 March 2023Available
13 March 2023Accepted
10 March 2023Submitted
Status: Peer Reviewed
Publication Status: In Press
Access rights to Published version: Open Access (Creative Commons)
Date of first compliant deposit: 28 April 2023
Date of first compliant Open Access: 28 April 2023
RIOXX Funder/Project Grant:
Project/Grant IDRIOXX Funder NameFunder ID
EP/N509796/1[EPSRC] Engineering and Physical Sciences Research Councilhttp://dx.doi.org/10.13039/501100000266
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