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Structural characterization of the acetonitrile complex NbCl5(MeCN)
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UNSPECIFIED (1997) Structural characterization of the acetonitrile complex NbCl5(MeCN). POLYHEDRON, 16 (3). pp. 351-353. ISSN 0277-5387.
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Abstract
The monosolvate (MeCN) of niobium(V) chloride has been structurally characterized. The metal is six coordinate with a somewhat distorted octahedral geometry in which the four equatorial chlorine atoms are coplanar but are clearly bent towards the bound axial acetonitrile ligand, mean N-ax-Nb-Cl-eq 83.62(12). The Nb-Cl bond distances lie in the range 2.249(2)-2.319(2) Angstrom and the metal to ligand distance, Nb-N, is 2.236(4) Angstrom. Copyright (C) 1996 Elsevier Science Ltd
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | POLYHEDRON | ||||
Publisher: | PERGAMON-ELSEVIER SCIENCE LTD | ||||
ISSN: | 0277-5387 | ||||
Official Date: | 1997 | ||||
Dates: |
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Volume: | 16 | ||||
Number: | 3 | ||||
Number of Pages: | 3 | ||||
Page Range: | pp. 351-353 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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