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Capture of mechanically interlocked molecules using rhodium-mediated terminal alkyne dimerisation
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Hood, Thomas M., Lau, S. and Chaplin, Adrian B. (2024) Capture of mechanically interlocked molecules using rhodium-mediated terminal alkyne dimerisation. RSC Advances , 14 (11). pp. 7740-7744. doi:10.1039/D4RA00566J ISSN 2046-2069.
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WRAP-capture-mechanically-interlocked-molecules-rhodium-mediated-terminal-alkyne-dimerisation-Chaplin-2024.pdf - Accepted Version Embargoed item. Restricted access to Repository staff only - Requires a PDF viewer. Download (1387Kb) |
Official URL: https://doi.org/10.1039/D4RA00566J
Abstract
The transition metal-mediated dimerisation of terminal alkynes is an attractive and atom-economic method for preparing conjugated 1,3-enynes. Using a phosphine-based macrocyclic pincer ligand, we demonstrate how this transformation can be extended to the synthesis of novel, hydrocarbon-based interlocked molecules: a rotaxane by ‘active’ metal template synthesis and a catenane by sequential ‘active’ and ‘passive’ metal template procedures.
Item Type: | Journal Article | ||||||
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Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||||
Journal or Publication Title: | RSC Advances | ||||||
Publisher: | Royal Society of Chemistry | ||||||
ISSN: | 2046-2069 | ||||||
Official Date: | 5 March 2024 | ||||||
Dates: |
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Volume: | 14 | ||||||
Number: | 11 | ||||||
Page Range: | pp. 7740-7744 | ||||||
DOI: | 10.1039/D4RA00566J | ||||||
Status: | Peer Reviewed | ||||||
Publication Status: | Published | ||||||
Access rights to Published version: | Open Access (Creative Commons) | ||||||
Date of first compliant deposit: | 12 February 2024 | ||||||
Date of first compliant Open Access: | 15 March 2024 | ||||||
Funder: | We thank the European Research Council (ERC, grant agreement 637313) and Royal Society (UF100592, UF150675, A.B.C.) for financial support. | ||||||
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