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C-H ACTIVATION AND NITRILE INSERTION REACTIONS OF A CATIONIC NIOBIUM ALKYLIDENE COMPLEX
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UNSPECIFIED (1995) C-H ACTIVATION AND NITRILE INSERTION REACTIONS OF A CATIONIC NIOBIUM ALKYLIDENE COMPLEX. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS (23). pp. 2421-2422. ISSN 0022-4936.
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Abstract
Oxidation of [Nb(eta(5)-C(5)H(4)Bu(t))(2)(CH(2)Ph)(2)] yields the stable cationic benzylidene complex [Nb(eta(5)-C(5)H(4)Bu(t))(2)(CHPh)(thf)]BPh(4), which readily loses thf to form the C-H activation product [Nb(eta(5)-C(4)H(4)Bu(t))(eta(5):eta(1)-C(5)H(4)CMe(2)CH(2))(eta(2)-CH(2)Ph)]BPh(4) and reacts with acetonitrile to give the double-insertion product [Nb(eta(5)-C(5)H(4)Bu(t))(2){eta(2)-NC(Me)C(Ph)C(Me)NH}]BPH4.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 0022-4936 | ||||
Official Date: | 7 December 1995 | ||||
Dates: |
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Number: | 23 | ||||
Number of Pages: | 2 | ||||
Page Range: | pp. 2421-2422 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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