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HYPODENTATE LIGANDS - SYSTEMATIC APPROACHES TO COMPLEXES CONTAINING DIDENTATE 2,2'/6',2''-TERPYRIDINE (TERPY) AND THE CRYSTAL AND MOLECULAR-STRUCTURES OF [RU(BIPY-N,N')(2)(TERPY-N,N')][PF6](2) AND [RU(BIPY-N,N')(2)(BTERPY-N,N')][PF6](2) (BIPY=2,2'-BIPYRIDINE, BTERPY=6-BROMO-2,2'/6',2''-TERPYRIDINE)
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UNSPECIFIED (1995) HYPODENTATE LIGANDS - SYSTEMATIC APPROACHES TO COMPLEXES CONTAINING DIDENTATE 2,2'/6',2''-TERPYRIDINE (TERPY) AND THE CRYSTAL AND MOLECULAR-STRUCTURES OF [RU(BIPY-N,N')(2)(TERPY-N,N')][PF6](2) AND [RU(BIPY-N,N')(2)(BTERPY-N,N')][PF6](2) (BIPY=2,2'-BIPYRIDINE, BTERPY=6-BROMO-2,2'/6',2''-TERPYRIDINE). JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (22). pp. 3571-3580. ISSN 0300-9246.
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Abstract
A series of complexes containing hypodentate didentate 2,2':6',2 ''-tetrpyridine (terpy) ligands of general formula [Ru(L-N,N')(2)(terpy-N,N')](2+) [L = 2,2'-bipyridine (bipy) or 1,10-phenanthroline] have been prepared. The complexes [Ru(bipy-N,N')(2)(terpy-N,N')][PF6](2) and [Ru(bipy-N,N')(2)(bterpy-N,N')][PF6](2) (bterpy = 6-bromo-2,2':6'2 ''-terpyridine) have been structurally characterised and shown to contain the didentate terpy ligand in the solid state.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 0300-9246 | ||||
Official Date: | 21 November 1995 | ||||
Dates: |
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Number: | 22 | ||||
Number of Pages: | 10 | ||||
Page Range: | pp. 3571-3580 | ||||
Publication Status: | Published |
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