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SYNTHESIS AND CHARACTERIZATION OF CATIONIC BIS(CYCLOPENTADIENYL)TUNGSTEN(IV) COMPLEXES CONTAINING ALKYL, CHLORIDE AND HYDRIDE LIGANDS
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UNSPECIFIED (1995) SYNTHESIS AND CHARACTERIZATION OF CATIONIC BIS(CYCLOPENTADIENYL)TUNGSTEN(IV) COMPLEXES CONTAINING ALKYL, CHLORIDE AND HYDRIDE LIGANDS. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (19). pp. 3125-3129. ISSN 0300-9246.
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Abstract
The cationic complexes [W(eta-C5H5)(2)R(NCMe)][PF6] (R = Et or H), [W(eta-C5H5)(2)Me(NCR')][BF4] and [W(eta-C5H5)(2)Cl(NCR')][BF4] (R' = Me or Ph) have been prepared and characterised by H-1 and C-13 NMR and IR spectroscopy, and by X-ray crystallography in the case of [W(eta-C5H5)(2)Et(NCMe)][PF6]. The complex [W(eta-C5H5)(2)H (NCMe)][PF6] is-unstable in solution at room temperature. decomposing slowly to yield the dinuclear C-H activation product [{W(eta - C5H5)(mu-eta(1):eta(5)-C5H4)(NCMe)}(2)][PF6](2) as demonstrated by NMR spectroscopy and X-ray crystallography.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 0300-9246 | ||||
Official Date: | 7 October 1995 | ||||
Dates: |
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Number: | 19 | ||||
Number of Pages: | 5 | ||||
Page Range: | pp. 3125-3129 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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