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(Z)-ETHYL 2-CYANO-3-METHYLSULFINYL-3-METHYLTHIOPROPENOATE
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UNSPECIFIED (1995) (Z)-ETHYL 2-CYANO-3-METHYLSULFINYL-3-METHYLTHIOPROPENOATE. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 51 (Part 8). pp. 1630-1632. ISSN 0108-2701.
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Abstract
The title compound, C8H11NO3S2, is shown to be formed in the oxidation of ethyl 2-cyano-3,3-bis(methyl-thio)propenoate with 3-chloroperoxybenzoic acid. The compound contains an (S-2)C=C(C-2) unit which is not exactly planar, as indicated by atomic deviations of +/-0.130(1)Angstrom from the least-squares plane through these six atoms. The C-S bond lengths are unexceptional but the bond between the CH3(O)S-group and the alkene C atom is slightly longer than expected [1.837 (3) Angstrom].
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | ||||
Publisher: | MUNKSGAARD INT PUBL LTD | ||||
ISSN: | 0108-2701 | ||||
Official Date: | 15 August 1995 | ||||
Dates: |
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Volume: | 51 | ||||
Number: | Part 8 | ||||
Number of Pages: | 3 | ||||
Page Range: | pp. 1630-1632 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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