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AZAMACROCYCLIC COMPLEXATION OF BISMUTH(III) - FORMATION AND STRUCTURE OF FAC-(BICL3-CENTER-DOT-ME(3)[9]ANEN(3)) WHERE ME(3)[9]ANEN(3)=1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE
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UNSPECIFIED (1995) AZAMACROCYCLIC COMPLEXATION OF BISMUTH(III) - FORMATION AND STRUCTURE OF FAC-(BICL3-CENTER-DOT-ME(3)[9]ANEN(3)) WHERE ME(3)[9]ANEN(3)=1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE. POLYHEDRON, 14 (2). pp. 315-318.
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Abstract
Addition of bismuth(III) chloride and the triaza macrocyclic ligand Me(3)[9]aneN(3) provided the dark yellow 1:1 adduct whose structure has been determined by X-ray diffraction. In the resulting half-sandwich arrangement the tridentate N-donor macrocycle and the three chlorine atoms occupy opposite faces of an octahedral bismuth(III) ion.
Item Type: | Journal Item | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | POLYHEDRON | ||||
Publisher: | PERGAMON-ELSEVIER SCIENCE LTD | ||||
ISSN: | 0277-5387 | ||||
Official Date: | January 1995 | ||||
Dates: |
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Volume: | 14 | ||||
Number: | 2 | ||||
Number of Pages: | 4 | ||||
Page Range: | pp. 315-318 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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