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STRUCTURE OF THE MONOMETHYLGALLIUM DERIVATIVE OF TMTAA (DIBENZOTETRA-METHYLTETRAAZA[14]ANNULENE)
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UNSPECIFIED (1993) STRUCTURE OF THE MONOMETHYLGALLIUM DERIVATIVE OF TMTAA (DIBENZOTETRA-METHYLTETRAAZA[14]ANNULENE). ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 49 (Part 7). pp. 1359-1361. ISSN 0108-2701.
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Abstract
The structure consists of a GaCH3 unit bound symmetrically to the four N atoms of the macrocycle with the metal atom 0.65 (1) angstrom above the N4 plane. The four N and C(methyl) atoms form a distorted square-based pyramidal geometry around the Ga atom. The average Ga-N bond distance is 2.016 (5) angstrom and the Ga-C distance of 1.958 (8) angstrom is fractionally shorter than the Ga-C distance of 1.967 (2) angstrom in Ga(CH3)3 [Beagley, Schmidling & Steer (1974). J. Mol. Struct. 21, 437-444].
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | ||||
Publisher: | MUNKSGAARD INT PUBL LTD | ||||
ISSN: | 0108-2701 | ||||
Official Date: | 15 July 1993 | ||||
Dates: |
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Volume: | 49 | ||||
Number: | Part 7 | ||||
Number of Pages: | 3 | ||||
Page Range: | pp. 1359-1361 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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