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SILVER(I) OXIDE-MEDIATED SYNTHESES OF 4-MEMBERED RING PLATINALACTONES
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UNSPECIFIED (1993) SILVER(I) OXIDE-MEDIATED SYNTHESES OF 4-MEMBERED RING PLATINALACTONES. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (14). pp. 2247-2250. ISSN 0300-9246.
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Abstract
Reaction of cis-[PtCl2(PPh3)2] with an excess of dialkyl malonate in the presence of silver(I) oxide afforded the platinalactone complexes [Pt{OC(O)CH(CO2R)}(PPh3)2] (R = Me or Et), via a novel cyclisation reaction. The platinalactone complexes have been fully characterised by NMR spectroscopy. Functionalised acetic acids containing activated hydrogens may also be used to synthesise four-membered ring platinalactones.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 0300-9246 | ||||
Official Date: | 21 July 1993 | ||||
Dates: |
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Number: | 14 | ||||
Number of Pages: | 4 | ||||
Page Range: | pp. 2247-2250 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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