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UNUSUAL CROWN-ETHER ENCAPSULATION OF A CHLOROSCANDIUM(III) CATION - STRUCTURE OF THREADED [SCCL2(18-CROWN-6)][SBCL6]
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UNSPECIFIED (1992) UNUSUAL CROWN-ETHER ENCAPSULATION OF A CHLOROSCANDIUM(III) CATION - STRUCTURE OF THREADED [SCCL2(18-CROWN-6)][SBCL6]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS (21). pp. 1619-1620. ISSN 0022-4936.
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Abstract
Halide abstraction from ScCl3 using SbCl5 provides the ScCl2+ cation, which is stabilised by crown ether complexation to give the ionic complex [ScC12(18-crown-6)][SbCl6]; the cation has a threaded structure in which the scandium is seven-coordinate (approximately pentagonal bipyramidal) and the crown adopts an unsymmetrical conformation leaving one oxygen site uncoordinated to the central metal.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 0022-4936 | ||||
Official Date: | 1 November 1992 | ||||
Dates: |
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Number: | 21 | ||||
Number of Pages: | 2 | ||||
Page Range: | pp. 1619-1620 | ||||
Publication Status: | Published |
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