The Library
MASS-SPECTROMETRIC STUDY OF STRUCTURE AND STEREOCHEMISTRY OF SOME STEREOISOMERIC FURANOSIDIC DERIVATIVES
Tools
UNSPECIFIED (1992) MASS-SPECTROMETRIC STUDY OF STRUCTURE AND STEREOCHEMISTRY OF SOME STEREOISOMERIC FURANOSIDIC DERIVATIVES. ORGANIC MASS SPECTROMETRY, 27 (10). pp. 1114-1120. ISSN 0030-493X.
Research output not available from this repository.
Request-a-Copy directly from author or use local Library Get it For Me service.
Abstract
A mass spectrometric study of eight new carbohydrate derivatives has been carried out to determine the influence of structure on the fragmentation mechanisms of stereoisomers. Results indicate that the relative intensities of peaks due to fragment ions of each pair of isomers are sometimes very different, especially those observed in the collision-induced decomposition mass spectra of [MH]+ ions. Metastable decompositions related to identical fragmentation processes of two isomers release different amounts of kinetic energy, however. It is usually observed that the kinetic energy released is larger for the S-configuration than for the R-configuration of the two epimers of a particular species.
Item Type: | Journal Article | ||||
---|---|---|---|---|---|
Subjects: | Q Science > QD Chemistry Q Science > QC Physics |
||||
Journal or Publication Title: | ORGANIC MASS SPECTROMETRY | ||||
Publisher: | JOHN WILEY & SONS LTD | ||||
ISSN: | 0030-493X | ||||
Official Date: | October 1992 | ||||
Dates: |
|
||||
Volume: | 27 | ||||
Number: | 10 | ||||
Number of Pages: | 7 | ||||
Page Range: | pp. 1114-1120 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
Request changes or add full text files to a record
Repository staff actions (login required)
View Item |