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REACTIVITY OF TETRAMETHYLENE BIRADICALS - THROUGH-BOND AND THROUGH-SPACE INTERACTIONS - 2 SINGLET ELECTRONIC STATES OF A BIRADICAL
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UNSPECIFIED (1992) REACTIVITY OF TETRAMETHYLENE BIRADICALS - THROUGH-BOND AND THROUGH-SPACE INTERACTIONS - 2 SINGLET ELECTRONIC STATES OF A BIRADICAL. THEOCHEM-JOURNAL OF MOLECULAR STRUCTURE, 93 . pp. 115-119. ISSN 0166-1280.
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Abstract
Consideration of through-bond and through-space interactions between the half-empty orbitals of the tetramethylene biradical leads to predictions concerning the cleavage/coupling ratio and the stereochemistry of tetramethylenes generated thermally and photochemically, and suggests that involvement of two low-lying singlet states of biradicals may be a general phenomenon. Some published experimental results are considered in the light of this analysis.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | THEOCHEM-JOURNAL OF MOLECULAR STRUCTURE | ||||
Publisher: | ELSEVIER SCIENCE BV | ||||
ISSN: | 0166-1280 | ||||
Official Date: | 31 July 1992 | ||||
Dates: |
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Volume: | 93 | ||||
Number of Pages: | 5 | ||||
Page Range: | pp. 115-119 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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