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A CONVENIENT HIGH-YIELD SYNTHESIS OF SOME TITANIUM(IV) OXO CLUSTER COMPOUNDS - CRYSTAL-STRUCTURE OF [TI3CL3(MU-O2CC6H4ME-P)5(MU-O)(MU-3-O)]
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UNSPECIFIED (1992) A CONVENIENT HIGH-YIELD SYNTHESIS OF SOME TITANIUM(IV) OXO CLUSTER COMPOUNDS - CRYSTAL-STRUCTURE OF [TI3CL3(MU-O2CC6H4ME-P)5(MU-O)(MU-3-O)]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (16). pp. 2529-2530. ISSN 0300-9246.
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Abstract
The reaction of TiCl4 with a series of para-substituted benzoic acids (p-XC6H4CO2H; X = Me, Et, F or l) yields the new trinuclear oxo clusters [Ti3Cl3(mu-O2CCH4X-p)5(mu-O)(mu-O)] in good yield; p-Bu(t)C66H4CO2H gives [{[TiCl(O2CR)2]2O}n] but p-MeOC6H4CO2H yields only a black intractable tar.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 0300-9246 | ||||
Official Date: | 21 August 1992 | ||||
Dates: |
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Number: | 16 | ||||
Number of Pages: | 2 | ||||
Page Range: | pp. 2529-2530 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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