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SYNTHESIS AND COORDINATION CHEMISTRY OF 1-(2',2''-BIPYRIDYL-5'-YL-METHYL)-1,4,8,11-TETRAAZACYCLOTETRADECANE L1 - QUENCHING OF FLUORESCENCE FROM [RU(BIPY)2(L1)]2+ BY COORDINATION OF NI(II) OR CU(II) IN THE CYCLAM CAVITY (BIPY = 2,2'-BIPYRIDINE, CYCLAM = 1,4,8,11-TETRA-AZACYCLOTETRADECANE)
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UNSPECIFIED (1992) SYNTHESIS AND COORDINATION CHEMISTRY OF 1-(2',2''-BIPYRIDYL-5'-YL-METHYL)-1,4,8,11-TETRAAZACYCLOTETRADECANE L1 - QUENCHING OF FLUORESCENCE FROM [RU(BIPY)2(L1)]2+ BY COORDINATION OF NI(II) OR CU(II) IN THE CYCLAM CAVITY (BIPY = 2,2'-BIPYRIDINE, CYCLAM = 1,4,8,11-TETRA-AZACYCLOTETRADECANE). JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS (9). pp. 684-687. ISSN 0022-4936.
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Abstract
A novel bipy derivative of cyclam (L1) designed for controlled and systematic polynuclear metal complex formation is reported; fluorescence quenching of the [Ru(bipy)3]2+ core of [(biPY)2Ru(L1)]2+ upon coordination of Cu(II) at the cyclam cavity is demonstrated.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 0022-4936 | ||||
Official Date: | 1 May 1992 | ||||
Dates: |
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Number: | 9 | ||||
Number of Pages: | 4 | ||||
Page Range: | pp. 684-687 | ||||
Publication Status: | Published |
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