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SINGLE LOCAL SITE STRUCTURE FOR VIBRATIONALLY DISTINCT ADSORPTION STATES - NO ON NI(111)
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UNSPECIFIED (1992) SINGLE LOCAL SITE STRUCTURE FOR VIBRATIONALLY DISTINCT ADSORPTION STATES - NO ON NI(111). CHEMICAL PHYSICS LETTERS, 192 (2-3). pp. 259-264. ISSN 0009-2614.
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Abstract
Scanned energy mode N and O 1s photoelectron diffraction data collected from NO on Ni(111) under conditions corresponding to three distinct N-O vibrational frequencies, previously assigned to different (bridge and atop) local adsorption configurations, show that NO in all cases occupies the same site. Comparison of these data with the results of theoretical simulations indicates that the common site is a threefold coordinated hollow. These results indicate that there is a need to reevaluate the range of applicability of the widely used method of adsorption site assignment based on the numerical values of internal molecular vibrational frequencies.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry Q Science > QC Physics |
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Journal or Publication Title: | CHEMICAL PHYSICS LETTERS | ||||
Publisher: | ELSEVIER SCIENCE BV | ||||
ISSN: | 0009-2614 | ||||
Official Date: | 1 May 1992 | ||||
Dates: |
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Volume: | 192 | ||||
Number: | 2-3 | ||||
Number of Pages: | 6 | ||||
Page Range: | pp. 259-264 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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