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BIOTRANSFORMATIONS USING CLOSTRIDIA - STEREOSPECIFIC REDUCTIONS OF A BETA-KETO ESTER
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UNSPECIFIED (1992) BIOTRANSFORMATIONS USING CLOSTRIDIA - STEREOSPECIFIC REDUCTIONS OF A BETA-KETO ESTER. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 (4). pp. 491-493. ISSN 0300-922X.
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Abstract
The reduction of methyl 4-(4-chlorophenylthio)-3-oxobutanoate 1 by clostridia has been studied. Clostridium pasteurianum ATCC 6013, C. tyrobutyricum DSM 1460 and C. kluyveri NCIB 10680 gave the D-(3S) reduction product 2, whereas C. kluyveri DSM 555 gave the L-(3R) reduction product 3. The products could be obtained in higher optical purities than by yeast reductions.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | ||||
Publisher: | ROYAL SOC CHEMISTRY | ||||
ISSN: | 0300-922X | ||||
Official Date: | February 1992 | ||||
Dates: |
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Number: | 4 | ||||
Number of Pages: | 3 | ||||
Page Range: | pp. 491-493 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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