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PREPARATION AND CHARACTERIZATION OF NOVEL ORGANOINDIUM DERIVATIVES - X-RAY CRYSTAL-STRUCTURE OF DIMETHYL(SALICYLALDEHYDE)INDIUM
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UNSPECIFIED (1991) PREPARATION AND CHARACTERIZATION OF NOVEL ORGANOINDIUM DERIVATIVES - X-RAY CRYSTAL-STRUCTURE OF DIMETHYL(SALICYLALDEHYDE)INDIUM. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 414 (3). pp. 285-293. ISSN 0022-328X.
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Abstract
The reaction of trimethylindium with one equivalent of salicylaldehyde, 2-carboxybenzaldehyde, 2-pyrrolidinone or N,N'-diphenylacetamidine results in the formation of the corresponding dimethylindium derivatives in good yields. The product obtained from the reaction with salicylaldehyde has been shown by a single crystal X-ray diffraction study to consist of centrosymmetric dimers with five-coordinate indium atoms, In-C 2.122(5), In-O(CHO) 2.341(4), In-O(OH) 2.188(3) and 2.383(3) angstrom. The reactions between triethylindium and phenylacetylene and ethanolamine are described.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Journal or Publication Title: | JOURNAL OF ORGANOMETALLIC CHEMISTRY | ||||
Publisher: | ELSEVIER SCIENCE SA LAUSANNE | ||||
ISSN: | 0022-328X | ||||
Official Date: | 27 August 1991 | ||||
Dates: |
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Volume: | 414 | ||||
Number: | 3 | ||||
Number of Pages: | 9 | ||||
Page Range: | pp. 285-293 | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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