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Copper(I) O,O '-dialkyldithiophosphate clusters : EXAFS, NMR and X-ray diffraction studies
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Rusanova, D., Christensen, K. E., Persson, I., Pike, K. J., Antzutkin, O. N. (Oleg N.), Zou, X., Dupree, Ray and Forsling, W. (2007) Copper(I) O,O '-dialkyldithiophosphate clusters : EXAFS, NMR and X-ray diffraction studies. Journal of Coordination Chemistry, Volume 60 (Number 5). pp. 517-525. doi:10.1080/00958970600842856 ISSN 0095-8972.
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Official URL: http://dx.doi.org/10.1080/00958970600842856
Abstract
Copper K- edge EXAFS data for six polycrystalline cubic cluster compounds, {Cu-8[ S2P(OR)(2)](6)(mu(8)- S)} with R= Et, Pr-n, Pr-i, Bu-n, Bu-i and Am-i, show that the architecture of their Cu-8(S2P)(2)S cores is fairly rigid and independent of both length and branching of the alkyl chain, and that the structure of the cluster is maintained in acetone solution. Solid- state P-31 CP-MAS and static Cu-65 NMR data for {Cu-8[S2P(O-n Pr)(2)] 6(mu(8)- S)} and {Cu-8[S2P(OEt)(2)](6) mu(8)- S)} show similarities in the icosahedral O,O'- dialkyldithiophosphate shells and in the `cubic' copper cores in these cluster compounds. The crystal structure of {Cu-8[S2P(O-n Pr)(2)](6) (mu(8)- S)} was resolved using single- crystal X- ray diffraction.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Physics | ||||
Journal or Publication Title: | Journal of Coordination Chemistry | ||||
Publisher: | Taylor & Francis Ltd. | ||||
ISSN: | 0095-8972 | ||||
Official Date: | 2007 | ||||
Dates: |
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Volume: | Volume 60 | ||||
Number: | Number 5 | ||||
Number of Pages: | 9 | ||||
Page Range: | pp. 517-525 | ||||
DOI: | 10.1080/00958970600842856 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published |
Data sourced from Thomson Reuters' Web of Knowledge
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