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Asymmetric opening of the epoxide ring in cyclohexene oxide by thiophenol using homochiral phosphinamide catalysts
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Nagasawa, Atsushi, Lin, Changxue and Wills, Martin (2007) Asymmetric opening of the epoxide ring in cyclohexene oxide by thiophenol using homochiral phosphinamide catalysts. Journal of Chemical Research, Volume 2007 (Number 1). pp. 1-4. doi:10.3184/030823407780199595 ISSN 0308-2342.
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Official URL: http://dx.doi.org/10.3184/030823407780199595
Abstract
Enantiomerically pure phosphinamides containing a pendant hydroxyl group catalyse the Al(III)-promoted ring opening of the meso epoxide in cyclohexene oxide with thiophenol in up to 80% enantiomeric excess.
Item Type: | Journal Article | ||||
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Subjects: | Q Science > QD Chemistry | ||||
Divisions: | Faculty of Science, Engineering and Medicine > Science > Chemistry | ||||
Journal or Publication Title: | Journal of Chemical Research | ||||
Publisher: | Science Reviews 2000 Ltd. | ||||
ISSN: | 0308-2342 | ||||
Official Date: | January 2007 | ||||
Dates: |
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Volume: | Volume 2007 | ||||
Number: | Number 1 | ||||
Number of Pages: | 4 | ||||
Page Range: | pp. 1-4 | ||||
DOI: | 10.3184/030823407780199595 | ||||
Status: | Peer Reviewed | ||||
Publication Status: | Published | ||||
Access rights to Published version: | Restricted or Subscription Access |
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